Classification and application of metal-based nanoantioxidants in medicine and healthcare

• Nguyen Nhat Nam,
• Nguyen Khoi Song Tran,
• Tan Tai Nguyen,
• Nguyen Ngoc Trai,
• Nguyen Phuong Thuy,
• Hoang Dang Khoa Do,
• Nhu Hoa Thi Tran and
• Kieu The Loan Trinh

Beilstein J. Nanotechnol. 2024, 15, 396–415, doi:10.3762/bjnano.15.36

• thyroid hormone disruption in zebrafish larvae co-exposed to tetrabromobisphenol A by promoting its bioaccumulation and bioavailability [192]. Xu et al. demonstrated that TiO2 nanoparticles can promote damage to adipose derived stromal cells at low concentrations [193]. Accordingly, the surface chemistry

Experimental investigation of usage of POE lubricants with Al₂O₃, graphene or CNT nanoparticles in a refrigeration compressor

• Kayhan Dağıdır and
• Kemal Bilen

Beilstein J. Nanotechnol. 2023, 14, 1041–1058, doi:10.3762/bjnano.14.86

• lubricants [2]. Sanukrishna and Prakash [3] experimentally investigated the thermophysical properties of a nanolubricant containing TiO2 nanoparticles for volume fractions of 0.07 to 0.8% in a temperature range of 20 to 90 °C. The results showed that the thermal conductivity and viscosity of the

Prediction of cytotoxicity of heavy metals adsorbed on nano-TiO₂ with periodic table descriptors using machine learning approaches

• Joyita Roy,
• Souvik Pore and
• Kunal Roy

Beilstein J. Nanotechnol. 2023, 14, 939–950, doi:10.3762/bjnano.14.77

• validation for all ML methods In order to determine if heavy metals and TiO2 nanoparticles had any cytotoxic effects, the selected eight important periodic table-based features were used. The final models developed with RF, AdaBoost, Gradient Boost, and Extreme Gradient Boost were evaluated using MAEtrain

Titania nanoparticles for photocatalytic degradation of ethanol under simulated solar light

• Evghenii Goncearenco,
• Iuliana P. Morjan,
• Claudiu Teodor Fleaca,
• Florian Dumitrache,
• Elena Dutu,
• Monica Scarisoreanu,
• Valentin Serban Teodorescu,
• Alexandra Sandulescu,
• Crina Anastasescu and
• Ioan Balint

Beilstein J. Nanotechnol. 2023, 14, 616–630, doi:10.3762/bjnano.14.51

• -Magurele, Romania National Institute of Materials Physics, Atomistilor Str., No. 405A, 077125, Bucharest-Magurele, Romania Romanian Academy, Inst. Phys. Chem. Ilie Murgulescu, 202 Spl. Independentei, 060021, Bucharest, Romania 10.3762/bjnano.14.51 Abstract TiO2 nanoparticles were synthesized by laser

• Degussa P25 sample. Two series of samples were obtained. Series “a” includes thermally treated TiO2 nanoparticles (to remove impurities) that have different proportions of the anatase phase (41.12–90.74%) mixed with rutile and small crystallite sizes of 11–22 nm. Series “b” series represents nanoparticles

• gas production has been detected for the samples from series “b”, whereas the CO2 evolution was observed for all samples from series “a”. Keywords: ethanol; H2 production; laser pyrolysis; photocatalyst; TiO2 nanoparticles; Introduction Semiconductor materials are widely used, from electronic

A TiO₂@MWCNTs nanocomposite photoanode for solar-driven water splitting

• Anh Quynh Huu Le,
• Ngoc Nhu Thi Nguyen,
• Hai Duy Tran,
• Van-Huy Nguyen and
• Le-Hai Tran

Beilstein J. Nanotechnol. 2022, 13, 1520–1530, doi:10.3762/bjnano.13.125

• mesoscale TiO2 [2][3]. This results in an improvement of the photon efficiency of TiO2 nanoparticles. Reducing the dimension of the photocatalyst favors not only a bandgap shift to the visible-light region but, unfortunately, also the recombination of photogenerated electrons and holes (e−/h+), which limits

• . This approach improves solar water splitting performance [7][9]. However, an excess amount of CNTs can deteriorate the photoactivity of TiO2 nanoparticles because CNTs block and cover the surface of TiO2 [9]. There are three categories of water splitting techniques applying photocatalysts, namely

• defects in the initial MWCNTs are hardly affected by the TiO2 nanoparticles. The TEM image also confirms that TiO2 nanoparticles only attach to some defects on the MWCNTs (Figure 3c) [17]. FTIR spectra of MWCNTs, TiO2, and the TiO2@MWCNTs nanocomposite are shown in Figure 6a. Regarding the spectrum of

Engineered titania nanomaterials in advanced clinical applications

• Padmavati Sahare,
• Paulina Govea Alvarez,
• Juan Manual Sanchez Yanez,
• Gabriel Luna-Bárcenas,
• Samik Chakraborty,
• Sujay Paul and
• Miriam Estevez

Beilstein J. Nanotechnol. 2022, 13, 201–218, doi:10.3762/bjnano.13.15

• reported by Rehman [8], who used the photodynamic properties of TiO2 for killing HeLa cancer cells. The hydrophobic nature of photosensitizers commonly used in photodynamic therapy led to selectivity and aggregation issues that jeopardize their effectiveness. Therefore, TiO2 nanoparticles (nps), which

• shell for the selective and rapid capture of peptides from human serum and urine samples [17]. Many studies have been published on using TiO2 nanotubes as photoelectrochemical glucose sensors for health purposes [18][19][20]. The present review focuses on contemporary research of TiO2 nanoparticles and

• . However, it is hydrophobic and poor cell adhesion has been reported. In a study of Kiran et al., TiO2 nanoparticles (0, 2, 5, and 7 wt %) were suspended in polycaprolactone forming a polymer/ceramic hybrid composite (PCL/TiO2), which was then used as a coating over biomedical grade commercial pure

A comprehensive review on electrospun nanohybrid membranes for wastewater treatment

• Senuri Kumarage,
• Imalka Munaweera and
• Nilwala Kottegoda

Beilstein J. Nanotechnol. 2022, 13, 137–159, doi:10.3762/bjnano.13.10

Morphology-driven gas sensing by fabricated fractals: A review

• Vishal Kamathe and
• Rupali Nagar

Beilstein J. Nanotechnol. 2021, 12, 1187–1208, doi:10.3762/bjnano.12.88

• , carbon monoxide, ammonia, nitrous oxide, and ethanol (Figure 10e,f) at 250 °C. The estimated fractal dimensions were 1.82 for the pore network and 1.72 for the foam sensor. Titanium oxide-based fractals Fusco et al. modified dielectric titanium oxide (TiO2) nanoparticles with fractal structure with a

Recent progress in magnetic applications for micro- and nanorobots

• Ke Xu,
• Shuang Xu and
• Fanan Wei

Beilstein J. Nanotechnol. 2021, 12, 744–755, doi:10.3762/bjnano.12.58

• to the human body or the environment caused by other materials such as lead. In addition, Gopal et al. [48] pointed out that boron exhibits diamagnetic properties in B-doped anatase TiO2 nanoparticles and showed photocatalytic activity in the visible-light range. Magnetic MNRs were applied to the

Bio-imaging with the helium-ion microscope: A review

• Matthias Schmidt,
• James M. Byrne and
• Ilari J. Maasilta

Beilstein J. Nanotechnol. 2021, 12, 1–23, doi:10.3762/bjnano.12.1

• HIM-SIMS was published by Lovric et al., who investigated E.coli bacteria exposed to TiO2 nanoparticles using the sector-field SIMS spectrometer [36]. In this review article, we build upon previous articles by Kim [37] and Gölzhäuser and Hlawacek [38] to present an overview on past discoveries and

• they investigated E.coli which were exposed to TiO2 nanoparticles with the sector-field spectrometer [36]. The authors report on secondary ion maps of CN− from the biomass as well as of Ti+ from the nanoparticles. So far, the mass resolution achieved does not allow for using HIM-SIMS to characterise

Unravelling the interfacial interaction in mesoporous SiO₂@nickel phyllosilicate/TiO₂ core–shell nanostructures for photocatalytic activity

• Bridget K. Mutuma,
• Xiluva Mathebula,
• Isaac Nongwe,
• Bonakele P. Mtolo,
• Boitumelo J. Matsoso,
• Rudolph Erasmus,
• Zikhona Tetana and
• Neil J. Coville

Beilstein J. Nanotechnol. 2020, 11, 1834–1846, doi:10.3762/bjnano.11.165

• photocatalyst with a degradation efficacy of 93% after three cycles. The porous flake-like morphology of the nickel phyllosilicate acted as a suitable support for the TiO2 nanoparticles. Further, a coating of TiO2 on the mSiO2@NiPS surface greatly affected the surface features and optoelectronic properties of

• good support for the TiO2 nanoparticles. Further, a coating of TiO2 on the SiO2@NiPS surface greatly impacted the surface features and optoelectronic properties of the core–shell nanostructure and yielded superior photocatalytic properties. Results and Discussion Morphological features, textural, and

• then added to the SiO2@NiPS material. The coverage of the spherical mSiO2@NiPS by aggregates of TiO2 nanoparticles to give mSiO2@NiPS/TiO2 can be clearly seen (Figure 1c and Figure 1f). EDX spectra confirmed the presence of nickel and silica in the mSiO2@NiPS, as well as that of nickel, titania, and

Antimicrobial metal-based nanoparticles: a review on their synthesis, types and antimicrobial action

• Matías Guerrero Correa,
• Fernanda B. Martínez,
• Cristian Patiño Vidal,
• Camilo Streitt,
• Juan Escrig and
• Carol Lopez de Dicastillo

Beilstein J. Nanotechnol. 2020, 11, 1450–1469, doi:10.3762/bjnano.11.129

• different morphologies and sizes. For example, the technique has been used to obtain ultrafine MgO nanoparticles (8–10 nm) [50], TiO2 nanoparticles (10–20 nm) [51], and even flower-like microstructures (diameter ≈6 µm) and microtubes (diameter ≈1 µm and length ≈4 µm) [52]. The sol–gel technique has been

Gram-scale synthesis of splat-shaped Ag–TiO₂ nanocomposites for enhanced antimicrobial properties

• Mohammad Jaber,
• Asim Mushtaq,
• Kebiao Zhang,
• Jindan Wu,
• Dandan Luo,
• Zihan Yi,
• M. Zubair Iqbal and
• Xiangdong Kong

Beilstein J. Nanotechnol. 2020, 11, 1119–1125, doi:10.3762/bjnano.11.96

• . The improvement in the antibacterial activity was attributed to the synergistic effect of the hybrid nature of TiO2 nanoparticles in the presence of Ag. Keywords: antimicrobial properties; biomaterials; nanocomposites; silver nanoparticles; titanium dioxide; Introduction The rapid industrial

• Gram-negative (E. coli) bacteria. Pure TiO2 nanoparticles and Ag–TiO2 nanocomposites showed clear inhibition zones of 3 mm, 4 mm, 14 mm and 19 mm against the Gram-negative E. coli bacteria (Figure 5b and c, respectively). In addition, 4 mm, 6 mm, 12 mm, and 19 mm inhibition zones were developed against

A novel dry-blending method to reduce the coefficient of thermal expansion of polymer templates for OTFT electrodes

• Xiangdong Ye,
• Bo Tian,
• Yuxuan Guo,
• Fan Fan and
• Anjiang Cai

Beilstein J. Nanotechnol. 2020, 11, 671–677, doi:10.3762/bjnano.11.53

• . González-Benito et al. [11] used high-energy ball cryomilling to uniformly disperse 5 wt % of titanium dioxide (TiO2) nanoparticles with a size of 65 nm within poly(ethylene-co-vinyl acetate) (EVA) to subsequently obtain a film of the composite with lower CTE by hot pressing. Ren et al. [12] first prepared

Correction: Photocatalytic antibacterial performance of TiO₂ and Ag-doped TiO₂ against S. aureus. P. aeruginosa and E. coli

• Kiran Gupta,
• R. P. Singh,
• Ashutosh Pandey and
• Anjana Pandey

Beilstein J. Nanotechnol. 2020, 11, 547–549, doi:10.3762/bjnano.11.43

• results of the article. XRD of TiO2 and Ag-doped TiO2 nanoparticles X-ray diffraction (XRD) was used to characterize as-prepared TiO2 and Ag-doped TiO2 nanoparticles. The diameter of crystalline TiO2, 3 wt % Ag-doped TiO2 and 7 wt % Ag-doped TiO2 nanoparticles annealed at 450 °C was calculated by the

• phase (2θ = 27.5°, compared with JCPDS file no. 00-021-1276), revealing the effect of calcination. As expected from previous works on similar Ag-doped TiO2 nanoparticles [1][2][3][4][5], the diffraction peaks associated with Ag were not easily observed. Similar to these prior works, the presence of Ag

• , complete rutile TiO2 phase was obtained [7]. It was previously reported that a mixture of anatase and rutile TiO2 nanoparticles has higher photocatalytic activity than pure anatase or pure rutile TiO2 nanoparticles under UV-light excitation [8]. Furthermore, it was shown that calcination of the

Improved adsorption and degradation performance by S-doping of (001)-TiO₂

• Xiao-Yu Sun,
• Xian Zhang,
• Xiao Sun,
• Ni-Xian Qian,
• Min Wang and
• Yong-Qing Ma

Beilstein J. Nanotechnol. 2019, 10, 2116–2127, doi:10.3762/bjnano.10.206

• further investigation. These include the differences between lightly and heavily doped TiO2 as well as the effects of S-doping on the crystal structure, the energy band structure and the chemical states of Ti and O. In this work, (001)-TiO2 nanoparticles (NPs) were first prepared, then S-doping was

TiO₂/GO-coated functional separator to suppress polysulfide migration in lithium–sulfur batteries

• Ning Liu,
• Lu Wang,
• Taizhe Tan,
• Yan Zhao and
• Yongguang Zhang

Beilstein J. Nanotechnol. 2019, 10, 1726–1736, doi:10.3762/bjnano.10.168

• electrochemical performance of Li/S batteries. The interlayer can capture the polysulfides due to the presence of oxygen functional groups and formation of chemical bonds. The hierarchically porous TiO2 nanoparticles are tightly wrapped in GO sheets and facilitate the polysulfide storage and chemical absorption

• . The excellent adhesion between TiO2 nanoparticles and GO sheets resulted in enhanced conductivity, which is highly desirable for an efficient electron transfer process. The Li/S battery with a TiO2/GO-coated separator exhibited a high initial discharge capacity of 1102.8 mAh g−1 and a 100th cycle

• . Conclusion In summary, a lightweight TiO2/GO coating, applied as an interlayer for Li/S batteries, has been prepared by using a simple method. The hierarchically porous TiO2 nanoparticles are tightly wrapped in GO sheets and formed a 3D network structure, which can capture the polysulfides by physical and

Novel hollow titanium dioxide nanospheres with antimicrobial activity against resistant bacteria

• Carol López de Dicastillo,
• Cristian Patiño,
• María José Galotto,
• Yesseny Vásquez-Martínez,
• Claudia Torrent,
• Daniela Alburquenque,
• Alejandro Pereira and
• Juan Escrig

Beilstein J. Nanotechnol. 2019, 10, 1716–1725, doi:10.3762/bjnano.10.167

• bacteria, including resistant E. coli and S. aureus strains, and when compared to commercial TiO2 nanoparticles, CSTiO2 nanospheres exhibited superior performance. In addition, the positive effect of UV irradiation on the antimicrobial activity was demonstrated. Keywords: antimicrobial nanoparticles

• was nevertheless successfully employed. Thus, hollow, spherical, antimicrobial nanostructures with a shell of 17 nm thickness were successfully obtained and antimicrobial results evidenced better performance than commercial TiO2 nanoparticles, principally against multidrug resistant bacteria such as

Kelvin probe force microscopy work function characterization of transition metal oxide crystals under ongoing reduction and oxidation

• Dominik Wrana,
• Karol Cieślik,
• Wojciech Belza,
• Christian Rodenbücher,
• Krzysztof Szot and
• Franciszek Krok

Beilstein J. Nanotechnol. 2019, 10, 1596–1607, doi:10.3762/bjnano.10.155

• catalytic activity of the TiO surface, which was previously postulated in the case of TiO/TiO2 nanoparticles [44]. Reduced titania TiO1.23 proves also to be a promising candidate for electrochemical water splitting [50]. As the catalytic activity of a crystalline rock-salt TiO phase has yet to be studied

BiOCl/TiO₂/diatomite composites with enhanced visible-light photocatalytic activity for the degradation of rhodamine B

• Minlin Ao,
• Kun Liu,
• Xuekun Tang,
• Zishun Li,
• Qian Peng and
• Jing Huang

Beilstein J. Nanotechnol. 2019, 10, 1412–1422, doi:10.3762/bjnano.10.139

• a carrier to support a layer of titanium dioxide (TiO2) nanoparticles and bismuth oxychloride (BiOCl) nanosheets. The results show that TiO2 nanoparticles and BiOCl nanosheets uniformly cover the surface of diatomite and bring TiO2 and BiOCl into close proximity. Rhodamine B was used as the target

• organic pollutant degradation [15]. However, according to previous studies, one limitation to its photocatalytic activity is that the photocatalytic process mainly occurs on the surface of the photocatalyst, which is a problem because the TiO2 nanoparticles readily agglomerate [10]. According to the

• used to study the morphology of the samples. The BiOCl sample is composed of lamellar crystals with poor dispersity, presenting an agglomeration morphology (Figure 4a). The SEM results of pure TiO2 show that the poor dispersion of the TiO2 nanoparticles leads to agglomeration, as shown in Figure 4b

Tailoring the stability/aggregation of one-dimensional TiO₂(B)/titanate nanowires using surfactants

• Atiđa Selmani,
• Johannes Lützenkirchen,
• Kristina Kučanda,
• Dario Dabić,
• Engelbert Redel,
• Ida Delač Marion,
• Damir Kralj,
• Darija Domazet Jurašin and
• Maja Dutour Sikirić

Beilstein J. Nanotechnol. 2019, 10, 1024–1037, doi:10.3762/bjnano.10.103

• tailor the stability of TNW dispersions and enabling better understanding of the surfactant behavior in contact with TNW surfaces. Conclusion The stability of the TiO2 nanoparticles, i.e., the size of nano- and microaggregates in aqueous environment, is known to be affected by their concentration, pH

Rapid, ultraviolet-induced, reversibly switchable wettability of superhydrophobic/superhydrophilic surfaces

• Yunlu Pan,
• Wenting Kong,
• Bharat Bhushan and
• Xuezeng Zhao

Beilstein J. Nanotechnol. 2019, 10, 866–873, doi:10.3762/bjnano.10.87

• switching and extreme wettability changes upon ultraviolet (UV) illumination were investigated. TiO2 nanoparticles were modified in solutions of trimethoxy(alkyl)silane, and the suspensions were sprayed on glass substrates. For such samples, the water contact angle (WCA) was shown to transition from a

• switchable wettability, the range of variation in the wettability is still limited [15][16]. Among the numerous approaches to achieve switchable wettability, UV illumination is highly preferred due to its environmentally friendly, non-contact and convenient manner. TiO2 nanoparticles are a common

• photocatalysis material that has attracted attention since it is more sensitive to UV light [17]. The use of a photochemical method to strengthen the interaction between nanoparticles and organic materials is quite common [18][19]. TiO2 nanoparticles modified with organic materials that have a low surface energy

An efficient electrode material for high performance solid-state hybrid supercapacitors based on a Cu/CuO/porous carbon nanofiber/TiO₂ hybrid composite

• Mamta Sham Lal,
• Thirugnanam Lavanya and
• Sundara Ramaprabhu

Beilstein J. Nanotechnol. 2019, 10, 781–793, doi:10.3762/bjnano.10.78

• carbon nanofiber/TiO2 (Cu/CuO/PCNF/TiO2) composite uniformly covered with TiO2 nanoparticles was synthesized by electrospinning and a simple hydrothermal technique. The synthesized composite exhibits a unique morphology and excellent supercapacitive performance, including both electric double layer and

• nanoparticles, which together open up new opportunities for energy storage and conversion applications. Keywords: composite; electrochemical performance; porous carbon nanofiber; solid-state hybrid supercapacitor; supercapacitor; TiO2 nanoparticles; Introduction To meet the rapidly growing demand for energy

• capacitance due to degradation of the electrode material, and thus poor electrochemical stability [16][17][18]. TiO2 nanoparticles loaded onto the carbon materials is a reasonable solution to overcome this challenge and is a potential electrode material for energy storage applications, ascribing to its low

On the transformation of “zincone”-like into porous ZnO thin films from sub-saturated plasma enhanced atomic layer deposition

• Alberto Perrotta,
• Julian Pilz,
• Stefan Pachmajer,
• Antonella Milella and
• Anna Maria Coclite

Beilstein J. Nanotechnol. 2019, 10, 746–759, doi:10.3762/bjnano.10.74

• ZnO [15][16]. Liang et al. [15] reported on the transformation of zincones deposited on TiO2 nanoparticles into porous ZnO via thermal treatment in the presence of air. Low surface area and wide pore size distribution (in the micropore and mesopore size range) were achieved. The surface area and the

Gold nanoparticles embedded in a polymer as a 3D-printable dichroic nanocomposite material

• Lars Kool,
• Anton Bunschoten,
• Aldrik H. Velders and
• Vittorio Saggiomo

Beilstein J. Nanotechnol. 2019, 10, 442–447, doi:10.3762/bjnano.10.43

• modifying 3D-printable plastics with, for example, catalysts [11] or TiO2 nanoparticles [12] to obtain new improved materials with special characteristics. In this paper, we show how to fabricate a 3D-printable dichroic material using gold nanoparticles, jumping from the 4th century Roman glassmiths